Dr. Martin Dornheim
Abteilungsleiter
Nanotechnologie
Telefon: +49 (4152) 87-2604
Telefax: +49 (4152) 87-2636
Arbeitsgebiete:
- Materialien für die Wasserstoffspeicherung
Fachlicher Hintergrund:
2010 | Co-Chair der Topical Conference "Hydrogen Storage System Engineering and Applications” im Rahmen der Tagung des "American Institute of Chemical Engineers”, Salt Lake City, UT, USA, November 2010 Co-Chair des "Symposium on Hydrogen Storage Technology, Fuel Cells and Lithium Ion Batteries” auf dem E-MRS Fall Meeting, Warschau, September 2010 Mitorganisator des "Brazilian-German Frontiers of Science and Technology Symposiums - BRAGFOST”, Session Chair der Session "Energy Conversion and Storage” , Brasilia, Brasilien, September 2010 Advisory board member des "5th Forum on New Materials – CIMTEC 2010”, Montecatini Terme, Italy, June 2010 |
2009 | Scientific committee member des "11th International Conference on Advanced Materials” in Rio de Janeiro, September 2009 |
seit 2009 | Sprecher des Helmholtz-Zentrum Geesthacht-Themenfeldes "Materialien für die Wasserstofftechnologie" |
Mär 2007 | "Invited Research Scientist " am "Energy Technology Research Institute – ETRI" des "National Institute of Advanced Industrial Science and Technology – AIST” in Tsukuba, Japan |
seit Jan 2006 | Experte der Internationalen Energieagentur Task 22 des "Hydrogen Implementation Agreements": " Fundamental and applied hydrogen storage materials development" |
Seit 2006 | Vertreter des Direktors des Teilinstituts Werkstofftechnologie am Institut für Werkstoffforschung |
seit Okt 2005 | Abteilungsleiter der Abteilung Nanotechnologie (WTN) am Institut für Werkstoffforschung, Helmholtz-Zentrum Geesthacht Geesthacht |
seit Apr 2005 | Lehrauftrag der Technischen Universität Hamburg-Harburg : "Physics of High Temperature Strength" |
Mär 2003 – Okt 2005 | Stellvertretender Abteilungsleiter der Abteilung Nanotechnologie am Institut für Werkstoffforschung, Helmholtz-Zentrum Geesthacht Geesthacht |
Aug 2002 – Feb 2003 | Stellvertretender Gruppenleiter der Arbeitsgruppe "Wasserstoff in Metallen", Institut für Materialphysik, Universität Göttingen |
Mai 2002 | Promotion an der Universität Göttingen |
Apr 1998 – Jul 2002 | wissenschaftlicher Mitarbeiter am Institut für Materialphysik der Universität Göttingen |
Apr 1995 – Apr 1998 | Stipendiat der Begabtenförderung der Friedrich-Naumann-Stiftung |
Sep 1994 – Aug 1998 | Physik-Diplomstudiengang an der Georg-August Universität Göttingen |
Sep 1992 – Aug 1994 | Physik-Diplomstudiengang an der Universität Hamburg |
1991 | Preisträger der Ernst-Hermann-Kölln-Stiftung |
Ausgewählte Veröffentlichungen:
Publikationen in Büchern
- M. Dornheim
"Tailoring Reaction Enthalpies of Hydrides”,
Chapter in Handbook of Hydrogen Storage, edited by M. Hirschler, Wiley-VCH (2010). - M. Dornheim , T. Klassen,
"FUELS-HYDROGEN STORAGE: High Temperature Hydrides”,
Chapter in Encyclopedia of Electrochemical Power Sources (2009) 459-472.
Artikel in Zeitschriften, Patente
- C. Pistidda, G. Barkhordarian, D. B. Minella, S. Garroni, F. Dolci, T. Jensen, U. Bösenberg, Y. Cerenius, W. Lohstroh, M. Fichtner, R. Bormann, M. Dornheim , "Formation of 2 NaBH4+MgH2 by Hydrogenation of 2NaH+MgB2", accepted for publication in Journal of Physical Chemistry C.
C. Pistidda, S. Garroni, F. Doci, A. Khandelwal, E.G. Bardaji, P. Nolis, M. Dornheim , R. Gosalawit, T. Jensen, Y. Cerenius, S. Surinach, M. D. Baro, W. Lohstroh, M. Fichtner, "Synthesis of amorphous Mg(BH4)2 from MgB2 and H2 at room temperature”, Journal of Alloys and Compds 508 (2010) 212-215.
U. Bösenberg, D.B. Ravnsbaek, H. Hagemann, V. D’anna, C. Bonatto Minella, C. Pistidda, W. van Beek, T.R. Jensen, R. Bormann, M. Dornheim , "Pressure and Temperature Influence on the Desorption Pathway of the LiBH4-MgH2 Composite System, J. Phys. Chem. C 114 (2010) 15212-15217.
G. Barkhordarian, C. Pistidda, M. Dornheim , R. Bormann,"Procedure for activation or regeneration of a hydrogen storage material", From Ger. (2010), DE 102008063895 B3 20100610, EP2199256 (A1), US2010160149 (A1), JP2010142804 (A1), CA2688774.
C. Bonatto Minella, G. Barkhordarian, S. Garroni, C. Pistidda, C. Rongeat, O. Gutfleisch, T.R. Jensen, Y. Cerenius, M. Dolors Baro, R. Bormann, M. Dornheim , "New Insights into the Effect of Transition Metal Fluorides on Reversible Formation of Ca(BH4)2”, submitted to J. Phys. Chem. C.
D. Pottmaier, C. Pistidda, E. Groppo, S. Bordiga, G. Spoto, M. Dornheim , M. Baricco, "Dehydrogenation reaction of 2 NaBH4+MgH2 system”, submitted to International Journal of Hydrogen Energy.
E. Deprez, A. Justo, T.C. Rojas, C. Lopez-Cartes, C. Bonatto Minella, U. Boesenberg, M. Dornheim , R. Bormann, A. Fernandez, " Microstructural study of the LiBH4+MgH2 Reactive Hydride Composite with and without Ti-isopropoxide additive ”, Acta Materialia58 (2010) 5683-5694.
S. Garroni, C. Milanese, A. Girella, A. Marini, G. Mulas, E. Menendez, C. Pistidda, M. Dornheim , S. Surinach, and M. D. Baro, "Sorption properties of NaBH4/MH2 (M=Mg, Ti) powder systems”, International Journal of Hydrogen Energy 35 (2010) 5434-5441.
T. K. Nielsen, U. Bösenberg, R. Gosalawit, M. Dornheim , Y. Cerenius, F. Besenbacher, T.R. Jensen, " A Reversible Nanoconfined Chemical Reaction ”, ACS Nano 4 (2010) 3903-3908.
E. Martinez-Franco, T. Klassen, M. Dornheim , R. Bormann, D. Jaramillo-Vigueras, ”Hydrogen sortpion properties of Ti-oxide/chloride catalyzed Na2LiAlH6”, Ceramic Transactions 209 (2010) 13-20.
G. A. Lozano, C.NaRanong, J.M. Bellosta von Colbe, R. Bormann, G. Fieg, J. Hapke, M. Dornheim , "Empirical Kinetic Model of Sodium Alanate Reacting System (I): Hydrogen Absorption”, International Journal of Hydrogen Energy 35 (2010) 6763-6772.
G. A. Lozano, C.NaRanong, J.M. Bellosta von Colbe, R. Bormann, G. Fieg, J. Hapke, M. Dornheim , "Empirical Kinetic Model of Sodium Alanate Reacting System (II): Hydrogen Desorption”, International Journal of Hydrogen Energy 35 (2010) 7539-7546.
U. Bösenberg, Ji Woo Kim, D. Gosslar, N. Eigen, T. R. Jensen, J.M. Bellosta von Colbe, Y. Zhou, M. Dahms, D. H. Kim, R. Günther, Y.W. Cho, K.H. OH, T. Klassen, R. Bormann, M. Dornheim , "Role of Additives in LiBH4-MgH2 Reactive Hydride Composites for Sorption Kinetics”, Acta Materialia 58 (2010) 3381-3389.
E. Deprez, Miguel A. Munoz-Marquez, Manuel A. Roldan, C. Prestipino, F. Javier Palomares, C. Bonatto Minella, U. Bösenberg, M. Dornheim , R. Bormann, A. Fernandez, "Oxidation State and Local Structure of Ti-Based Additives in the Reactive Hydride Composite 2LiBH4+MgH2”, Journal of Physical Chemistry C 114 (2010) 3309-3317.
R. Gosalawit, J. M. Bellosta von Colbe, M. Dornheim , T.R. Jensen, Y. Cerenius, K. Suarez, C.M. Bonatto Minella, M. Peschke, R. Bormann, "LiF-MgB2 system for Reversible Hydrogen Storage”, Journal of Physical Chemistry C 114 (2010) 10291-10296.
C.N. Ranong, M. Hoehne, J. Franzen, J. Hapke, G. Fieg, M. Dornheim , N. Eigen, J. Bellosta von Colbe, O. Metz, "Concept, Design and Manufacture of a Prototype Hydrogen Storage Tank Based on Sodium Alanate”, Chemical Engineering & Technology, 32 (2009) 1154-1163.
N. Eigen, U. Bösenberg, J. Bellosta von Colbe, T. R. Jensen, Y. Cerenius, M. Dornheim, T. Klassen, R. Bormann, "Reversible hydrogen storage in NaF-Al composites", J. Alloys and Compounds 477 (2009) 76-80.
N. Eigen, M. Dornheim, R. Bormann, "Hydrogen-storing composite materials", From Ger. Offen. (2009), DE 102007054843 A1 20090520, WO2009062850 (A1), EP2215010 (A1), CA2707987 (A1).
Sabrina Sartori, Xiumei Qi, Nico Eigen, Jiri Muller, Thomas Klassen, Martin Dornheim, Bjørn C. Hauback , "A search for new Mg- and K-containing alanates for hydrogen storage”, International Journal of Hydrogen Energy 34 (2009) 4582-4586.
Ulrike Bösenberg, Ulla Vainio, Philipp Klaus Pranzas, Jose M Bellosta Von Colbe, Günther Goerigk, Edmund Welter, Martin Dornheim, A Schreyer and R Bormann, "On the chemical state and distribution of Zr- and V-based additives in reactive hydride composites”, Nanotechnology 20 (2009) 204003 1-9.
C. Na Ranong, M. Hoehne, J. Franzen, J. Hapke, G. Fieg, M. Dornheim, " Model-assisted pilot-plant-scale process-technological design of a sodium alanate-based metal hydride storage device ", Chemie Ingenieur Technik (2009), 81(5), 645-654.
Aline Léon, Oleg Zabara, Sabrina Sartori, Nico Eigen, Martin Dornheim, Thomas Klassen, Jiri Muller, Bjørn Hauback, Maximilian Fichtner, " Investigation of (Mg, Al, Li, H)-based hydride and alanate mixtures produced by reactive ball milling ", Journal of Alloys and Compounds 476 (2009) 425-428.
Gustavo A. Lozano, Nico Eigen, Claude Keller, Martin Dornheim, Ruediger Bormann, "Effects of heat transfer on the sorption kinetics of complex hydride reacting systems”, International Journal of Hydrogen Energy (2009), 34(4), 1896-1903.
Robert L. Corey, Timothy M. Ivancic, David T. Shane, Erik A. Carl, Robert C., Jr. Bowman, Jose M. Bellosta von Colbe, Martin Dornheim , Rüdiger Bormann, Jaques Huot, Ragaiy Zidan, Ashley C. Stowe, Mark S. Conradi, "Hydrogen Motion in Magnesium Hydride by NMR”, Journal of Physical Chemistry C 112(49) (2008) 19784-19790.
N. Eigen, F. Gosch, M. Dornheim , T. Klassen, R. Bormann, "Improved hydrogen sorption of sodium alanate by optimized processing”, Journal of Alloys and Compounds 465 (1-2) (2008), 310-316.
Borgschulte, A. Züttel, P. Hug, G. Barkhordarian, N. Eigen, M. Dornheim , R. Bormann, A. J. Ramirez-Cuesta, "Hydrogen-deuterium exchange experiments to probe the decomposition reaction of sodium alanate”, Physical Chemistry Chemical Physics (2008), 10(27), 4045-4055.
J.R. Ares, K.F. Aguey-Zinsou, M. Porcu, J.M. Sykes, M. Dornheim, T. Klassen, R. Bormann, "Thermal and mechanically activated decomposition of LiAlH4”, Mat. Res. Bull. 43 (2008) 1263-1275.
A. Borgschulte, M. Bielmann, A. Zuettel, G. Barkhordarian, M. Dornheim, R. Bormann, "Hydrogen dissociation on oxide covered MgH2 by catalytically active vacancies", Appl. Surf. Science 254 (2008) 2377-2384.
G. Barkhordarian, T.R. Jensen, S. Doppiu, U. Bösenberg, A. Borgschulte, R. Gremaud, R. Cerenius, M. Dornheim, T. Klassen, R. Bormann, "Formation of Ca(BH4)2 from hydrogenation of CaH2+MgB2 composites”, J. of Phys. Chem. C 112 (2008) 2743-2749.
Lene Mosegaard, Bitten Møller, Jens-Erik Jørgensen, Ulrike Bösenberg, Martin Dornheim, Jonathan C. Hanson, Yngve Cerenius, Hans Jørgen Jakobsen, Flemming Besenbacher, Torben R. Jensen, "Intermediate Phases Observed During Decomposition of LiBH4", J. Alloys and Compds. 446-447 (2007) 301-305.
Gagik Barkhordarian, Thomas Klassen, Martin Dornheim and Rüdiger Bormann, "Unexpected kinetic effect of MgB2 in reactive hydride composites containing complex borohydrides", Journal of Alloys and Compds., 440 (2007) L18-L21.
J.R. Ares Fernandez, F. Aguey-Zinsou, M. Elsaesser, X.Z. Ma, M. Dornheim, T. Klassen and R. Bormann, "Mechanical and thermal decomposition of LiAlH4 with metal halides", Int. J. of Hydrogen Energy 32 (2007) 1033-1040.
T. Klassen, M. Dornheim, R. Bormann, U. Baumgart, "Gastight tank provided with a diffusion barrier layer containing metal hydrides for low-molecular mediums especially hydrogen", From Ger. Offen. (2007), DE 102005048714 A1 20070426, US 20070089764.
U. Boesenberg, S. Doppiu, L. Mosegaard, A. Borgschulte, N. Eigen, G. Barkhordarian, T. R. Jensen, Y. Cerenius, O. Gutfleisch, T. Klassen, M. Dornheim, R. Bormann, "Hydrogen sorption properties of MgH2-2LiBH4 composites", Acta Materialia 55 (2007) 3951-3958.
Phillip Klaus Pranzas, Martin Dornheim, Ulrike Boesenberg, Jose Ramon Ares Fernandez, Guenter Goerigk, Stephan Volkher Roth, Rainer Gehrke and Andreas Schreyer, "Small-Angle Scattering Investigations of Magnesium Hydride used as Hydrogen Storage Material”, J. Applied Crystallography 40 (2007) 262-269.
D. Zander, L. Lyubenova, U. Köster, T. Klassen and M. Dornheim, "Influence of the Nb2O5 distribution on the electrochemical hydrogenation of nanocrystalline magnesium", Journal of Alloys and Compounds 434-435 (2007) 753-755.
Nico Eigen, Claude Keller, Martin Dornheim , Thomas Klassen and Rüdiger Bormann, " Industrial production of light metal hydrides for hydrogen storage ", Viewpoint Set in Scripta Materialia 56 (2007) 847-851.
M. Dornheim , S. Doppiu, G. Barkhordarian, U. Boesenberg, T. Klassen, O. Gutfleisch, R.Bormann, "Hydrogen Storage in Magnesium-Based Hydrides and Hydride Composites", Viewpoint Set on Mg-based hydrogen storage materials, Viewpoint Set in Scripta Materialia 56 (2007) 841-846.
times cited according to Web of Science: 58Borgschulte, U. Bösenberg, G. Barkhordarian, M. Dornheim and R. Bormann, "Enhanced hydrogen sorption kinetics of magnesium by destabilized MgH2− δ ", Catalysis Today 120 (2007) 262-269.
P.K. Pranzas, M. Dornheim, D. Bellmann, K.-F. Aguey-Zinsou, T. Klassen and A. Schreyer, "SANS/USANS investigations of nanocrystalline MgH2 for reversible storage of hydrogen", Physica B: Condensed Matter 385-386 ( 2006) 630-632.
M. Dornheim , N. Eigen, G. Barkhordarian, T. Klassen, R. Bormann, "Tailoring Hydrogen Storage Materials Towards Application", Advanced Engineering Materials 8 (2006) 377-385.
times cited according to Web of Science: 55D. Zander, L. Lyubenova, U. Köster, M. Dornheim, F. Aguey-Zinsou and T. Klassen,"The catalytic effect of Nb2O5 on the electrochemical hydrogenation of nanocrystalline magnesium", Journal of Alloys and Compounds 413 (2006) 298-301.
Friedrichs, J.C. Sánchez-López, C. López-Cartes, M. Dornheim, T. Klassen, R. Bormann and A. Fernández, "Chemical and microstructural study of the oxygen passivation behaviour of nanocrystalline Mg and MgH2", Applied Surface Science 252 (2006) 2334-2345.
X.Z. Ma, E. Martinez-Franco, M. Dornheim, T. Klassen and R. Bormann,"Catalyzed Na2LiAlH6 for hydrogen storage", Journal of Alloys and Compounds 404-406 (2005) 771-774.
P.-A. Huhn, M. Dornheim, T. Klassen and R. Bormann, "Thermal stability of nanocrystalline magnesium for hydrogen storage", Journal of Alloys and Compounds 404-406 (2005) 499-502.
S. Deledda, A. Borissova, C. Poinsignon, W.J. Botta, M. Dornheim and T. Klassen,"H-sorption in MgH2 nanocomposites containing Fe or Ni with fluorine", Journal of Alloys and Compounds, (2005) 409-412 .
S. Doppiu, P. Solsona, T. Spassov, G. Barkhordarian, M. Dornheim, T. Klassen, S. Suriñach and M.D. Baró, "Thermodynamic properties and absorption–desorption kinetics of Mg87Ni10Al3 alloy synthesised by reactive ball milling under H2 atmosphere ", Journal of Alloys and Compounds, Volumes 404-406 ( 2005) 27-30.
D. Zander, Lyudmilla Lyubenova, U. Köster, T. Klassen, M. Dornheim, "Hydrogenation of Nanocrystalline Mg-based Alloys” in”Hydrogen Storage Materials”, eds. M. Nazri, G-A. Nazri, R.C. Young, C. Ping, Mat.Res. Soc.Symp.Proc. (Warrendale 2004), Vol. 801, BB 3.1.
P.K. Pranzas, M. Dornheim, J.R. Ares, K.-F. Aguey-Zinsou, V. Leiner, T. Klassen, A. Schreyer, G. Goerigk, "ASAXS study of the catalyst distribution in nanostructured MgH2/MexOy", Hamburger Synchrotron Labor Annual Report 161-162 (2004).
M. Dornheim , T. Klassen, R. Bormann, " Hydrogen Storage Materials", http://www.jsps.go.jp/j-bilat/asi/data_2004/L18.pdf
M. Dornheim , S. J. van der Molen, E. S. Kooij, J. Kersemakers, H. Harms, U. Geyer, R. Griessen, R. Kirchheim und A. Pundt, "Stress development in thin Y-films on hard substrates during hydrogen loading, J. Appl. Phys. 93, 8958 – 8965 (2003).
A. Pundt, M. Dornheim, H. Guerdane, H. Teichler, H. Ehrenberg, M. T. Reetz, und N. M. Jisrawi, ”Evidence for cuboctahedral to icosahedral transition of quasi-free Pd-H clusters controlled by the hydrogen content" Eur. Phys. J D 19, 333-337 (2002).
M. Dornheim , A. Pundt, "Stresses and Strains in thin films under hydrogen loading”,Hamburger Synchrotron Labor Annual Report 907-908 (2001).
M. Dornheim , N. Jisrawi, K. Nörthemann, O. Dankert, J. Cizek, J. Bankmann, C. Bähtz, M. Knapp und A. Pundt, "Non-equilibrium behavior and phase boundaries in Yttrium-H, Gadolinium-H and Niobium-H thin films". Hamburger Synchrotron Labor Annual Report 907-908 (2001).
M. Dornheim , N. Jisrawi, E. S. Kooij und A. Pundt, "Determination of out-of-plane strains and phase boundaries in hydrogen loaded Yttrium- and Niobium thin films" ,Hamburger Synchrotron Labor Annual Report 473-474 (2000),
M. Dornheim und H. Teichler, "Atomistic Modeling of Misfit Dislocations for Ge/(001) Si and Ge/(111) Si”, phys. stat. sol. (a) 171 (1999) 267.
M. Dornheim und H. Teichler, "Atomistic Modeling of Misfit Dislocation Network Variants for Ge/Si(111) Interfaces”, phys. stat. sol (b) 222 (2000) 101.
